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. 2022 Oct 24;13(45):13418–13425. doi: 10.1039/d2sc05079j

PLQYs and photophysical parameters of radicals in dichloromethane.

λ em (nm) Φ f (%) τ/ns k f/107 s−1 k nr/107 s−1
PyBTMa 585 2 6.4 0.3 14
F2PyBTMb 566 4 12.5 0.3 7.7
PyPBTM 654 9.5 12 0.8 7.5
MesPyBTM 645 30 26 1.2 2.7
Mes2PyBTM 628 47 38 1.2 1.4
Mes2F2PyBTM 623 66 44 1.5 0.8
a

Cited from ref. 11.

b

Cited from ref. 18. All Φfs were obtained by absolute PLQY measurement.