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. 2022 Oct 26;13(45):13409–13417. doi: 10.1039/d2sc05160e

Estimated round-trip efficiencies Inline graphic calculated using the difference in energy potentials. Common for hydrogen, formic acid, and methanol we use UOER = 1.6 VRHE and UORR = 0.8 VRHE.

Energy stored (electrolyzer) Energy released (fuel cell) Round trip efficiency, η
Hydrogen U HER = −0.1 VRHE U HOR = 0.1 VRHE ≈41%
Formic acid U CO2→HCOOH = −0.8 VRHE U FAOR = 0.2 VRHE ≈25%
Methanola U CO2→CO+H2 = −0.6 VRHE U CO→CO2 = 0.65 VRHE ≈7%
Li-batteryb ≈90%
a

Here only the cost of syngas production is considered, not the full formation of methanol.

b

Typical charge/discharge efficiency.