Table 2. Summary of DLS Diameters (D_H)^a Obtained for Aqueous Dispersions of Diblock Copolymer Micelles at 25 °C by SD^b and by PIM^c.

	DH (nm)
polymer	SDb	PIMc
H66-b-G275	phase separation at H2O > 80%	N/Ad
H38-b-G475	39 ± 2	30 ± 2
H73-b-G475	phase separation at H2O > 80%	40 ± 2
H93-b-G975	34 ± 2	32 ± 2
H75-b-G269G96	phase separation	138 ± 2e
H68-b-G264G911	phase separation	49 ± 2
H45-b-G253G922	34 ± 2	29 ± 2
H60-b-G253G922	39 ± 2	26 ± 2
H67-b-G222G953	59 ± 2	24 ± 2

^aMean value of three measurements ± difference between maximum and minimum values.

^bPolymers were dissolved in DMF and then water was slowly added to 80% (w/w %). Residual DMF was removed by dialysis. Final polymer concentration: 1.5 mg mL^–1 in water.

^c1.5 mg mL^–1 polymer in water with 1.5 equiv of NaOH, resulting in a measured pH 11–11.5. HCl (0.1 M) was then gradually added to reach pH 4.5–5.

^d1.5 mg mL^–1 polymer in water at pH 12.4. After polymer addition, the measured pH was 12.3. HCl (0.1 M) was then gradually added and phase separation occurred at pH < 10.4.

^e1.5 mg mL^–1 polymer in water at pH 12.6. After polymer addition, the measured pH was 12.5. HCl (0.1 M) was then gradually added to reach pH 4.