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. 2022 Nov 21;27(22):8072. doi: 10.3390/molecules27228072

Table 3.

Acute (% ARfD) and chronic (% ADI) risk assessment of pesticide residues in vegetable and fruit samples exceeding maximum residue levels using two consumption rates (0.1 kg for chronic risk and 0.2 kg for acute risk) in different population groups.

Pesticides/Samples ARfD Acute Dietary Exposure (%ARfD) ADI Chronic Dietary Exposure (%ADI)
Child A Teenager B Adult C Child A Teenager B Adult C
Vegetables:
Carrot
Lufenuron 0.0150 8.80 3.77 2.20 0.015 2.76 1.18 0.69
Cabbage
Chlorpyrifos 0.0100 1.33 0.57 0.33 0.01 0.49 0.21 0.12
Cucumber
Chlorfenapyr 0.0150 3.20 1.37 0.80 0.015 1.27 0.55 0.32
Chlorpyrifos 0.0100 13.33 5.71 3.33 0.01 3.96 1.70 0.99
Fenvalerate 0.0125 8.53 3.66 2.13 0.0125 3.50 1.50 0.88
Fipronil 0.0090 1.63 0.70 0.41 0.0002 36.67 15.71 9.17
Imidacloprid 0.0800 0.53 0.23 0.13 0.06 0.24 0.10 0.06
Methomyl 0.0025 25.60 10.97 6.40 0.0025 12.80 5.49 3.20
Oxamyl 0.0010 22.67 9.71 5.67 0.001 11.33 4.86 2.83
Thiophanate methyl 0.2000 0.67 0.29 0.17 0.08 0.71 0.30 0.18
Eggplant
Chlorpyrifos 0.0100 1.47 0.63 0.37 0.01 0.73 0.31 0.18
Propargite 0.0600 0.24 0.10 0.06 0.03 0.24 0.10 0.06
Green Beans
Lufenuron 0.0150 40.27 17.26 10.07 0.015 14.59 6.25 3.65
Green Onion
Chlorpyrifos 0.0100 2.53 1.09 0.63 0.01 0.84 0.36 0.21
Profenofos 1.0000 1.27 0.54 0.32 0.03 21.13 9.06 5.28
Green Peas
Chlorpyrifos 0.0100 2.13 0.91 0.53 0.01 1.07 0.46 0.27
Lufenuron 0.0150 8.53 3.66 2.13 0.015 3.01 1.29 0.75
Okra
Chlorpyrifos 0.0100 1.87 0.80 0.47 0.01 1.07 0.46 0.27
Deltamethrin 0.0100 1.47 0.63 0.37 0.01 0.73 0.31 0.18
Fenvalerate 0.0125 5.33 2.29 1.33 0.0125 1.44 0.62 0.36
Fipronil 0.0090 3.85 1.65 0.96 0.0002 86.67 37.14 21.67
Propargite 0.0600 0.31 0.13 0.08 0.03 0.31 0.13 0.08
Pepper
Carbendazim 0.0200 22.00 9.43 5.50 0.02 7.76 3.32 1.94
Chlorpyrifos 0.0100 3.20 1.37 0.80 0.01 1.60 0.69 0.40
Dimethoate 0.0020 7.33 3.14 1.83 0.002 3.67 1.57 0.92
Fluazifop-p-butyl 0.0170 7.06 3.03 1.76 0.01 5.16 2.21 1.29
Methomyl 0.0025 32.00 13.71 8.00 0.0025 8.53 3.66 2.13
Profenofos 1.0000 0.05 0.02 0.01 0.03 0.78 0.33 0.19
Potatoes
Chlorpyrifos 0.0100 1.73 0.74 0.43 0.01 0.90 0.39 0.23
Lufenuron 0.0150 10.67 4.57 2.67 0.015 3.87 1.66 0.97
Spinach
Chlorpyrifos 0.0100 1.60 0.69 0.40 0.01 0.80 0.34 0.20
Lambda-cyhalothrin 0.0050 138.93 59.54 34.73 0.0025 115.82 49.64 28.96
Omethoate 0.0020 8.00 3.43 2.00 0.002 4.00 1.71 1.00
Tomato
Chlorpyrifos 0.0100 6.93 2.97 1.73 0.01 3.47 1.49 0.87
Lambda-cyhalothrin 0.0050 19.20 8.23 4.80 0.0025 13.78 5.90 3.44
Propargite 0.0600 4.87 2.09 1.22 0.03 3.38 1.45 0.84
Thiophanate methyl 0.2000 1.40 0.60 0.35 0.08 1.36 0.58 0.34
Zucchini
Chlorpyrifos 0.0100 2.13 0.91 0.53 0.01 3.20 1.37 0.80
Diazenon 0.0250 0.59 0.25 0.15 0.0002 36.67 15.71 9.17
Fipronil 0.0090 4.89 2.10 1.22 0.0002 110.00 47.14 27.50
Imidacloprid 0.0800 9.02 3.86 2.25 0.06 3.56 1.53 0.89
Lambda-cyhalothrin 0.0050 18.13 7.77 4.53 0.0025 32.27 13.83 8.07
Thiophanate methyl 0.2000 0.70 0.30 0.18 0.08 0.88 0.38 0.22
Fruites:
Apple
Chlorpyrifos 0.0100 52.53 22.51 13.13 0.01 13.02 5.58 3.26
Fipronil 0.0090 2.52 1.08 0.63 0.0002 56.67 24.29 14.17
Fluazifop-p-butyl 0.0170 1.25 0.54 0.31 0.01 1.07 0.46 0.27
Imidacloprid 0.0800 1.02 0.44 0.25 0.06 0.39 0.17 0.10
Propargite 0.0600 0.44 0.19 0.11 0.03 0.40 0.17 0.10
Apricot
Buprofezin 0.5000 0.53 0.23 0.13 0.01 9.80 4.20 2.45
Carbendazim 0.0200 22.67 9.71 5.67 0.02 7.72 3.31 1.93
Chlorpyrifos 0.0100 41.47 17.77 10.37 0.01 12.20 5.23 3.05
Dimethoate 0.0020 9.33 4.00 2.33 0.002 4.67 2.00 1.17
Imidacloprid 0.0800 0.68 0.29 0.17 0.06 0.29 0.12 0.07
Metamitron 0.1000 2.92 1.25 0.73 0.03 2.41 1.03 0.60
Profenofos 1.0000 0.31 0.13 0.08 0.03 3.45 1.48 0.86
Cantaloupe
Dates
Chlorpyrifos 0.0100 1.87 0.80 0.47 0.01 0.93 0.40 0.23
Omethoate 0.0020 35.33 15.14 8.83 0.002 17.67 7.57 4.42
Grapes
Carbendazim 0.0200 37.93 16.26 9.48 0.02 9.23 3.96 2.31
Chlorfenapyr 0.0150 15.29 6.55 3.82 0.015 4.43 1.90 1.11
Chlorpyrifos 0.0100 3.20 1.37 0.80 0.01 1.38 0.59 0.34
Dimethoate 0.0020 72.00 30.86 18.00 0.002 24.44 10.48 6.11
Omethoate 0.0020 29.33 12.57 7.33 0.002 9.33 4.00 2.33
Thiacloprid 0.0200 20.00 8.57 5.00 0.01 11.16 4.78 2.79
Thiophanate methyl 0.2000 4.23 1.81 1.06 0.08 3.07 1.31 0.77
Guava
Chlorpyrifos 0.0100 2.40 1.03 0.60 0.01 1.20 0.51 0.30
Fipronil 0.0090 2.52 1.08 0.63 0.0002 56.67 24.29 14.17
Lambda-cyhalothrin 0.0050 6.40 2.74 1.60 0.0025 4.62 1.98 1.16
Methomyl 0.0025 66.13 28.34 16.53 0.0025 33.07 14.17 8.27
Kaki
Chlorpyrifos 0.0100 16.40 7.03 4.10 0.01 8.20 3.51 2.05
Dimethoate 0.0020 660.00 282.86 165.00 0.002 258.33 110.71 64.58
Fluazifop-p-butyl 0.0170 2.04 0.87 0.51 0.01 1.73 0.74 0.43
Lambda-cyhalothrin 0.0050 33.60 14.40 8.40 0.0025 23.02 9.87 5.76
Mango
2 phenylphenol 0.4000 0.20 0.08 0.05 0.4 0.08 0.03 0.02
Chlorfenapyr 0.0150 1.87 0.80 0.47 0.015 0.93 0.40 0.23
Chlorpyrifos 0.0100 1.60 0.69 0.40 0.01 0.80 0.34 0.20
Orange
Chlorpyrifos 0.0100 1.47 0.63 0.37 0.01 0.73 0.31 0.18
Strawberry
Carbendazim 0.0200 17.93 7.69 4.48 0.02 5.01 2.15 1.25
Chlorpyrifos 0.0100 40.13 17.20 10.03 0.01 12.89 5.52 3.22
Omethoate 0.0020 661.33 283.43 165.33 0.002 191.67 82.14 47.92
Thiophanate methyl 0.2000 2.07 0.89 0.52 0.08 1.60 0.68 0.40

Acute risk (% ARfD) and Chrinic risk (% ADI) were calculated with data of ARfD and ADI from European Commision pesticide residue database. Values of ADI were used when ARfD values were missing with pesticides lufenuron, chlorpyrifos, fenvalerate, dimethoate, omethoate, and 2-phenylphenol. The weight of different population groups used is (A) children (15 kg), (B) teenagers (35 kg), and (C) adults (60 kg).