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. 2022 Nov 18;23(22):14363. doi: 10.3390/ijms232214363

Table 1.

The results of the characterisation of materials in the form of: P—raw polymer, C—solvent cast composite plate, R—thermally extruded rods. TGA: filler content; GPC: Mn—number average molecular weight, Mw—weight average molecular weight, PDI—polydispersity index; DSC (second heating): Tg—transition temperature, Tccr—cold crystallisation temperature, Hccr—cold crystallisation enthalpy, Tm—melting temperature, Hm—melting enthalpy, ΔH/w—enthalpy of crystalline phase in the polymeric matrix of the sample, w—content of polymer in the sample.

Material Form Filler Content ± SD [%] Mn
[kDa]
Mw
[kDa]
PDI Tg [°C] Tccr [°C]/ΔHccr [J/g] Tm [°C]/ΔHm [J/g] ΔH/w [J/g]
PCL-1010-BH P 125.7 229.0 1.8 −61.6 - 57.9/59.3 59.3
C 19.9 ± 0.2 126.8 198.8 1.6 −63.0 - 56.2/51.7 64.5
R 19.8 ± 0.6 120.1 195.9 1.6 −62.9 - 57.0/53.5 66.6
PLC70-1010-BH P 99.1 173.4 1.7 30.3 128.0/1.7 159.8/1.8 0.1
C 19.7 ± 0.4 84.7 161.9 1.8 30.1 106.4/14.8 158.8/15.4 0.7
R 20.1 ± 1.2 64.2 142.2 2.2 26.9 89.8/17.2 160.0/18.6 1.8
PLC85-1010-BH P 71.9 228.4 3.2 42.5 - - 0.0
C 19.3 ± 0.6 73.7 228.3 3.1 42.1 - - 0.0
R 19.9 ± 0.3 58.8 207.0 3.5 42.6 - - 0.0
PLG82-1010-BH P 122.8 220.2 1.8 58.7 - - 0.0
C 19.8 ± 0.5 125.2 227.7 1.8 57.0 - - 0.0
R 19.8 ± 0.4 56.5 151.1 2.7 54.6 - - 0.0