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. 2022 Nov 28;9(4):303–322. doi: 10.1007/s40521-022-00326-1

Table 2.

Summary of anaphylaxis mediators, cell source, testing characteristics, and evidence of their potential use as biomarkers in anaphylaxis (1–7, 9–22, 24, 27–40, 42–90)

Mediator Source Recommended sampling time Methods available for routine assessment Correlation with severe anaphylaxis Half-life
Preformed
Histamine (plasma, urine) MC, BS NT 0–30 min Yes Yes  < 15 min
Histamine (24-h urine) MC, BS, NT 0–24 h Yes Yes UNK (0–24 h)
N-m-histamine (plasma, 24-h urine) MC, BS, NT 0–24 h Yes Yes UNK (0–24 h)
N-m-imidazole acetic acid (24-h urine) MC, BS, NT 0–24 h Yes UNK UNK (0–24 h)
Tryptase (serum/plasma) MC, BS 15 min–3 h Yes Yes  ~ 2 h
Chymase (serum) MC, BS 0–24 h No Yes  > 24 h
Carboxypeptidase A3 (serum/plasma) MC, BS 0–8 h No UNK  > tryptase (2–8 h)
Basogranulin (serum) BS UNK No No UNK
Heparin (plasma) MC, BS UNK No Yes UNK
DPPI/cathepsin C (serum) MC, BS UNK No UNK UNK (similar to histamine)
Cathepsin G (serum) MC, BS, EOS, NT UNK No UNK UNK
Newly generated over minutes
Bradykinin (plasma) Plasma UNK No Yes  < 1 min
FXII, PK, HK, thrombin (plasma) Plasma UNK FXII, thrombin UNK UNK
LTE4 (24-h urine, plasma) MC, BS, EOS, NT, MAC 0–24 h No Yes 7 min
LTB4, LTC4, LTD4 (24-h urine) MC, BS, NT 0–24 h No UNK  < 7 min
PGD2 (serum) MC, EOS, NT, MN, PT 0–24 h No Yes 30 min
9α,11β-PGF2 (serum) MC, PT UNK (5–15 min) No UNK UNK
2,3-dinor-11β-PGF2α (24-h urine) MC, PT UNK (0–24 h) No UNK UNK
TXA2 (serum/plasma, urine) MC, EOS, PT UNK No UNK 30 s
TXB2 (serum/plasma, urine) MC UNK No UNK 60 min
PAF* (plasma) MC, BS, EOS, NT, MAC, MN, PT, EC UNK No Yes  < 5 min
PAF-AH (serum) MC, MAC, PT plasma UNK No Yes 30 min
Nitric oxide EC UNK No UNK UNK
C3a, C5a (plasma) Plasma UNK No No UNK
TNF-α* (serum/plasma) MC, MAS, NT, MAC UNK Yes UNK 30 min
Newly generated over hours
Stem cell factor (serum/plasma) MC UNK No Yes** UNK
TGF-β (serum/plasma) MC, EOS UNK Yes UNK, potential**

2–3 min active

90 min latent**

CXCL4/PF4, PDGF PT UNK No UNK  < 3 min
IL-1b (serum/plasma) MC, NT 0–15 min No UNK 19 min**
IL-2, IL-22 (serum/plasma) MC 0–10 h No IL-2 yes UNK
IL-4/IL-13 (serum/plasma) MC, BS, EOS UNK (0–24 h) No IL-4 yes** 35–90 min
IL-10 (serum/plasma) MC, EOS UNK (0–24 h) Yes Yes 1–3.5 h
IL-6 (serum/plasma) MC, BS, NT, MAC UNK (0–24 h) Yes Yes 2–6 h
IL-8 (serum/plasma) MC, EOS, NT UNK (< 3 h) No No  < 4 h
CCL2/MCP-1 (serum/plasma) MC, NT, MAC, MN, EC UNK (0–30 min) No UNK, potential 30 min
CCL5/RANTES (serum/plasma) MC, EOS, MN UNK No UNK 14–18 h
MPO (serum/plasma) NT, MN UNK (< 5 h) No Yes UNK 4–5 h**
Other possible biomarkers (source cells) Chondroitin sulfate (MC, BS), elastase* (NT), TSLP (MC, EC, SMC), IL-31 (MC, BS, EOS, MAC, LT), IL-33 (MC, BS), IL-3/IL-5/IL-16/IL-18 (MC, EOS), IL-17 (NT), IL-23/IL-27/FGF (MAC), G-CSF (MC, NT, MAC, MN, EC), GM-CSF (MC, BS, EC), M-CSF (MC, MN, EC), VEGF (MC, MAC, PT), S1P (MC, PT, EC, ERY), IFN- γ (NT, LT, NK), endothelin-1 (MC, MAC, MN, EC, SMC), prostacyclin (MC, PT, EC, SMC), plasminogen activator (MC), MBP (EOS)

MC, mast cell; BS, basophil; NT, neutrophil; PT, platelet; EOS, eosinophil; MAC, macrophage; MN, monocyte; EC, endothelial cell; SMC, smooth muscle cell; ERY, erythrocyte; LT, T lymphocyte; NK, natural killer cell; N-m, N-methyl; DPPI, dipeptidyl peptidase I; FXII, coagulation factor XII; PK, prekallikrein; HK, high molecular weight kininogen; PAF, plasmin activator factor; PAF-AH, acetylhydrolase; LTE4, E4 leukotriene; LTB4, B4 leukotriene; LTC4, C4 leukotriene; LTD4, D4 leukotriene; PGD2, D2 prostaglandin; TXA2, A2 thromboxane; TXB2, B2 thromboxane; TGF-β, tumor grow factor beta; TNF-α, tumor necrosis factor alpha; CXCL4/PF4, platelet factor 4; PDGF, platelet-derived growth factor; TSLP, thymic stromal lymphopoietin; FGF, fibroblast grow factor; G-CSFR, granulocyte colony stimulating factor receptor; GM-CSFR, granulocyte–macrophage colony-stimulating factor receptor; M-CSF, VEGF CCL2/MCP-1 CCL5/RANTES S1P; MPO, myeloperoxidase; MBP, major basic protein; IFN-γ, interferon gamma

*Also preformed, but mainly newly generated

**Studies performed in mammals, not in humans