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. 2022 Nov 28;12(52):33928–33935. doi: 10.1039/d2ra06580k

Comparison of spectrum constants of low excited electronic states of the same main group ions of SeBr+.

Λ–S states Monovalent molecules T e/cm−1 R e ω e/cm−1 B e/cm−1 ω e χ e/cm−1
X 3Σ SCl+22 0 1.8779 686.1 0.2839 3.12
SeCl+23 0 2.0351 520.8 0.1686 1.9586
TeCl+24 0 2.2287 448.9 0.1237 1.5727
SeBr+ 0 2.1802 378.5 0.0905 1.0977
11Δ SCl+22 6334 1.8763 691.0 0.2844 2.89
SeCl+23 6415 2.0310 527.7 0.1693 1.8346
TeCl+24 6183 2.2244 455.0 0.1241 1.4745
SeBr+ 5733 2.1776 381.7 0.0907 1.0549
11Σ+ SCl+22 11 171 1.8818 675.1 0.2828 3.22
SeCl+23 11 755 2.0374 513.3 0.1682 2.1417
TeCl+24 11 787 2.2289 446.6 0.1236 1.6931
SeBr+ 10 343 2.1890 366.1 0.0897 1.2493