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. 2022 Nov 4;16(11):17572–17592. doi: 10.1021/acsnano.2c06827

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© 2022 The Authors. Published by American Chemical Society

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Engineering of SACs with axial functionalization. (a, b) PCo immobilized on graphene with or without diphenyl sulfide functionalization, (c) current density in differential pulse voltammograms for [PCo]⁻ to PCo oxidation, (d) Faradaic efficiencies of CO production, and (e) a possible electron transfer pathway.³⁷ (f) Immobilization of Co^IICNPY on CNTs with diverse ligand axial functionalization and (g) free energy profiles for the CO₂RR.¹⁰² (a-e) Reproduced with permission from ref (37). Copyright 2020 Wiley-VCH. (f-g) Reproduced with permission from ref (102). Copyright 2021 Wiley-VCH.