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. 2022 Nov 30;12(53):34335–34345. doi: 10.1039/d2ra05779d

Arrhenius parameters for the degradation of MG and CV under UV-365.

Dye T (K) k 2 (L min−1 mol−1) A (s−1) E act (kJ mol−1) R 2 ΔH (kJ mol−1) ΔS (kJ mol−1 K−1) ΔG (kJ mol−1)
MG 293 0.7 × 10−3 1.55 × 105 46.89 0.991 44.45 −0.153 89.41
303 1.2 × 10−3 44.37 −0.154 91.10
313 2.4 × 10−3 44.28 −0.153 92.30
CV 293 1.1 × 10−3 3.20 × 106 52.96 0.985 50.52 −0.128 88.31
303 2.6 × 10−3 50.44 −0.127 89.15
313 4.4 × 10−3 50.35 −0.129 90.73