Arrhenius parameters for the degradation of MG and CV under UV-365.
Dye | T (K) | k 2 (L min−1 mol−1) | A (s−1) | E act (kJ mol−1) | R 2 | ΔH (kJ mol−1) | ΔS (kJ mol−1 K−1) | ΔG (kJ mol−1) |
---|---|---|---|---|---|---|---|---|
MG | 293 | 0.7 × 10−3 | 1.55 × 105 | 46.89 | 0.991 | 44.45 | −0.153 | 89.41 |
303 | 1.2 × 10−3 | 44.37 | −0.154 | 91.10 | ||||
313 | 2.4 × 10−3 | 44.28 | −0.153 | 92.30 | ||||
CV | 293 | 1.1 × 10−3 | 3.20 × 106 | 52.96 | 0.985 | 50.52 | −0.128 | 88.31 |
303 | 2.6 × 10−3 | 50.44 | −0.127 | 89.15 | ||||
313 | 4.4 × 10−3 | 50.35 | −0.129 | 90.73 |