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. 2022 Oct 20;2(11):2522–2528. doi: 10.1021/jacsau.2c00392

Table 2. Applicability Study of α-(Hetero)Aryl Amines.

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a

Reaction conditions: ammonium salt (1) (0.15 mmol, 1.0 equiv), NiBr2·(diglyme) (12 mol %), L3 (15 mol %), CO2/NH3 (15/15 mL), Zn (1.2 equiv), ZnF2 (50 mol %), NMP:diglyme (0.5:0.1 mL), 120 °C, 28 h. Isolated yields.

b

NiBr2 (12 mol %), dppe (12 mol %), NMP:toluene (0.5:0.1 mL), 120 °C, 24 h. Isolated yields.

c

GC yields reported using n-tetradecane as the internal standard.

d

30 h. rr represents the ratio of the major product to the sum of all other isomers as determined by GC analysis.