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. 2022 Nov 9;13(46):13851–13856. doi: 10.1039/d2sc05423j

Attempts to replace electricity with chemical oxidantsa.

graphic file with name d2sc05423j-u2.jpg
Entry Oxidant 4, yielda (conv., %) 27, yielda (conv., %)
1 Anode 68 (>95) 70 (>95)
2 NFSI n.d. (11) n.d. (51)
3 TBHP n.d. (20) n.d. (73)
4 CAN n.d. (36) n.d. (35)
5 m-CPBA n.d. (14) n.d. (22)
6 DDQ n.d. (15) n.d. (91)
7 PhI(OAc)2 n.d. (30) n.d. (>95)
8 Mn(OAc)3 n.d. (69) n.d. (>95)
9 AgNO3 n.d. (>95) n.d. (>95)
a

Yield and conversion were determined by NMR of the crude reaction mixture with PhOCF3 or CH2Br2 as the internal standard; n.d. = not detected.