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. Author manuscript; available in PMC: 2023 Dec 5.
Published in final edited form as: Angew Chem Int Ed Engl. 2022 Nov 2;61(49):e202212814. doi: 10.1002/anie.202212814

Table 1.

Ruthenium-JOSIPHOS-catalyzed C-C coupling of methylallene 1a or butadiene 1b with alcohol 2a to form adduct 3a and stereochemical model for carbonyl addition.a

graphic file with name nihms-1841591-t0003.jpg
a

Yields of material isolated by silica gel chromatography. Enantioselectivities were determined by HPLC analysis. TFE = trifluoroethanol.

b

THF,

c

Isoctane.

See Supporting Information for further details.