Table 2. Spin–Lattice Relaxation Time at Crystallographically Inequivalent Carbon Nuclei Sites of Prednisone, Prednisolone, Prednisolone Acetate, Methylprednisolone, and Methylprednisolone Acetate.
| prednisone |
prednisolone |
prednisolone
acetate |
methylprednisolone |
methylprednisolone
acetate |
|||||
|---|---|---|---|---|---|---|---|---|---|
| carbon nuclei | relaxation time (s) | carbon nuclei | relaxation time (s) | carbon nuclei | relaxation time (s) | carbon nuclei | relaxation time (s) | carbon nuclei | relaxation time (s) |
| C20 | 388 ± 20 | C20 | 211 ± 10 | C20 | 192 ± 10 | C20 | 180 ± 5 | C20 | 118 ± 5 |
| C3 | 600 ± 30 | C3 | 355 ± 20 | C3 | 306 ± 10 | C3 | 170 ± 5 | C3 | 164 ± 10 |
| C5 | 397 ± 20 | C5 | 262 ± 12 | C5 | 172 ± 10 | C5 | 70 ± 2 | C5 | 68 ± 5 |
| C1 | 422 ± 20 | C1 | 255 ± 14 | C1 | 212 ± 10 | C1 | 170 ± 5 | C1 | 162 ± 10 |
| C2 | 357 ± 20 | C2 | 285 ± 20 | C2 | 252 ± 10 | C2 | 165 ± 5 | C2 | 166 ± 10 |
| C4 | 418 ± 20 | C4 | 282 ± 20 | C4 | 210 ± 10 | C4 | 80 ± 2 | C4 | 72 ± 5 |
| C17 | 337 ± 20 | C17 | 200 ± 20 | C17 | 157 ± 10 | C17 | 116 ± 5 | C17 | 105 ± 5 |
| C11 | 388 ± 20 | C11 | 265 ± 20 | C11 | 233 ± 10 | C11 | 145 ± 5 | C11 | 133 ± 5 |
| C21 | 422 ± 20 | C21 | 190 ± 10 | C21 | 205 ± 10 | C21 | 145 ± 5 | C21 | 78 ± 5 |
| C9 | 264 ± 20 | C9 | 246 ± 10 | C9 | 214 ± 10 | C9 | 160 ± 5 | C9 | 146 ± 5 |
| C14 | 338 ± 20 | C14 | 246 ± 10 | C14 | 170 ± 10 | C14 | 120 ± 5 | C14 | 134 ± 5 |
| C13 | 187 ± 10 | C13 | 115 ± 10 | C13 | 50 ± 3 | C13 | 37 ± 2 | C13 | 45 ± 5 |
| C10 | 187 ± 10 | C10 | 135 ± 10 | C10 | 85 ± 5 | C10 | 110 ± 5 | C10 | 70 ± 5 |
| C12 | 400 ± 20 | C12 | 210 ± 12 | C12 | 170 ± 10 | C12 | 90 ± 2 | C12 | 109 ± 5 |
| C7 | 400 ± 20 | C7 | 270 ± 10 | C7 | 209 ± 10 | C7 | 115 ± 5 | C7 | 17 ± 2 |
| C16 | 408 ± 20 | C16 | 217 ± 10 | C16 | 230 ± 10 | C16 | 116 ± 5 | C16 | 96 ± 5 |
| C6 | 420 ± 20 | C6 | 236 ± 10 | C6 | 176 ± 10 | C6 | 30 ± 2 | C6 | 120 ± 5 |
| C8 | 420 ± 20 | C8 | 285 ± 10 | C8 | 185 ± 10 | C8 | 120 ± 5 | C8 | 120 ± 5 |
| C15 | 387 ± 20 | C15 | 242 ± 10 | C15 | 184 ± 10 | C15 | 120 ± 5 | C15 | 100 ± 5 |
| C18, C19 | 5 ± 2 | C18, C19 | 5 ± 1 | C18, C19 | 5 ± 2 | C18, C19 | 5 ± 1 | C18C19 | 10 ± 2 |
| C23 | 10 ± 2 | C22 | 5 ± 1 | C23 | 10 ± 2 | ||||
| C22 | 206 ± 10 | C22 | 83 ± 5 | ||||||
| C24 | 10 ± 2 | ||||||||