Table 3.
Summary of representative waste-derived electrocatalysts for OWE
Waste | Catalyst | Electrolyte | E10a (V) | Durability | Refs |
---|---|---|---|---|---|
Camellia flower | S-doped carbon | 1.0 M KOH | 1.76 | 24 h @ ~ 20 mA cm−2 | [174] |
Corn stalks | Few-layer N-doped porous carbon | 1.0 M KOH | 1.60 | – | [173] |
Rose flower | Ni-doped graphitic carbon | 1.0 M KOH | 1.64 | 24 h @ 1.64 V | [176] |
Textile sludge | Fe, N co-doped carbon | 1.0 M KOH | 1.70 | 14 h @ 1.7 V | [177] |
Battery industrial wastewater | NiCoMn LTHs | Alkaline wastewaterb | 1.58 | 24 h @ 1.6 V | [39] |
Spent Li-ion batteries | Ni/Ni-Mn-Co–O | 1.0 M KOH | 1.62 | 25 h @ 1.58 – 1.66 V | [178] |
Scrap copper wires | NiCoP/Cu | 1.0 M KOH | 1.59 | 24 h @ 10 mA cm−2 | [77] |
Cornstalks | β-Mo2C/C | 1.0 M KOH | 1.65 | 30 h @ 10 mA cm−2 | [215] |
Cotton fibers | Co/carbon tubes | 1.0 M KOH | 1.40 | 110 h @ 1.4 V | [179] |
Miscanthus stems | Co/C | 1.0 M KOH | 1.45 | 120 h @ 50 mA cm−2 | [47] |
Duckweed | NiFe-alloy/N, S-doped carbon | 1.0 M KOH | 1.61 | 200 h @ 2 V | [181] |
Alfalfa | NiFe/N, P, S co-doped carbon | 1.0 M KOH | 1.60 | 50 h @ 10 mA cm−2 | [182] |
Grapefruit peels | NiFe-alloy/ N-doped carbon | 1.0 M KOH | 1.63 | – | [180] |
Magnolia leaves | CoP/C | 1.0 M KOH | 1.56 | 24 h @ 1.59 V | [216] |
Polysaccharide chitin | Co2P/N, P co-doped carbon | 1.0 M KOH | 1.65 | 10 h @ ~ 20 mA cm−2 | [190] |
Ginkgo leaves | Co2P@CoP/C | 1.0 M KOH | 1.63 | 1000 min @ 10 mA cm−2 | [189] |
Cauliflower leaves | Ni/NiO/N-doped carbon | 0.1 M KOH | 1.688 | 20 h @ 10—30 mA cm−2 | [188] |
Amaranth | Fe, N co-doped carbon | 1.0 M KOH | 1.53 | 30 h @ 1.53 V | [183] |
Lotus leaves | Co/MoO2@N doped carbon | 1.0 M KOH | 1.629 | 48 h @ 10 mA cm−2 | [186] |
Holly leaves | Co-CoO/C | 1.0 M KOH | 1.77 | – | [187] |
Chicken feathers | Ni-Co oxides/C | 1.0 M KOH | 1.53 | 200 h @ 1.7 V | [185] |
Willow catkins | Co3O4/N-doped hollow carbon | 1.0 M KOH | 1.74 | 20 h @ 1.74 V | [184] |
Waste yeast | Cu8S5 decorated N, S co-doped porous carbon | 1.0 M KOH | 1.64 | 14 h @ 10 mA cm−2 | [191] |
Tissue paper | Co9S8@Co–N/C nanorods | 1.0 M KOH | 1.61 | 70 h @ 10 mA cm−2 | [192] |
Catkin | MoS2@NiOOH@C | 1.0 M KOH | 1.62 | 40 h @ 1.62 V | [194] |
Willow catkins | NiFe LDH/(NiFe)Sx/hollow carbon | 1.0 M KOH | 1.53 | 100 h @ 10 mA cm−2 | [48] |
Spent Li-ion batteries | CoN/graphene | 1.0 M KOH | 1.61 | 40 h @ 1.68 V | [195] |
aE10: Applied voltage at the current density of 10 mA cm−2
bAlkaline wastewater: Wastewater with 1 M KOH