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. 2022 Nov 29;55(Pt 6):1572–1582. doi: 10.1107/S1600576722009888

Table 2. Mean elemental weight fractions of pyrite concentrate powder ball milled for 7 min determined using semi-quantitative WD-XRF data, and standard deviations from five repeat samples.

The Kα peak of oxygen was visible but O was excluded from the analysis due to the lack of accuracy for this element. The presence of trace elements with overlapping energies, such as As Kα and Pb Lα, or W Lβ and Au Lα, was confirmed by ICP-MS (Table S1). Other elements are below the detection/quantification limit of the technique (Loubser & Verryn, 2008; Kadachi & Al-Eshaikh, 2012). Elemental fractions were obtained from fundamental parameter analysis.

Element Wt% Element Wt%
S 52.2 (6) Mg 0.032 (4)
Fe 35.8 (3) K 0.03 (10)
Si 4.51 (10) Zr 0.01 (2)
Al 0.95 (2) W <0.01
Na 0.74 (4) As <0.01
Ti 0.57 (4) Pb <0.01
Co 0.45 (2) Nd <0.01
Ni 0.058 (8) Y <0.01
Ca 0.042 (13)