Table 2.
Kinetic parameters of adsorption of Cr6+ ions to the activated TETA-PP
| Parameter | PFO | PSO | |||||||
|---|---|---|---|---|---|---|---|---|---|
| Activated TETA-PP (g/L) | Cr6+ conc. (mg/L) | qe (exp.) | qe (calc.) | k1 × 103 | R2 | qe (calc.) | k2 × 103 | h | R2 |
| 1.0 | 100 | 99.45 | 39.500 | 13.588 | 0.974 | 100.00 | 0.92 | 9225 | 0.997 |
| 150 | 147.33 | 39.537 | 5.527 | 0.761 | 131.58 | 1.68 | 29070 | 1.000 | |
| 200 | 188.70 | 56.403 | 3.224 | 0.576 | 156.25 | 1.50 | 36630 | 0.996 | |
| 250 | 229.76 | 70.648 | 5.067 | 0.976 | 200.00 | 0.79 | 31447 | 0.998 | |
| 300 | 246.34 | 65.268 | 3.685 | 0.989 | 212.77 | 1.18 | 53476 | 1.000 | |
| 400 | 326.56 | 78.886 | 3.455 | 0.926 | 285.71 | 1.03 | 84034 | 1.000 | |
| 1.5 | 100 | 66.67 | 4.300 | 8.291 | 0.767 | 65.79 | 14.72 | 63694 | 1.000 |
| 150 | 100.00 | 27.791 | 14.739 | 0.896 | 101.01 | 1.45 | 14793 | 0.999 | |
| 200 | 132.65 | 16.665 | 5.988 | 0.905 | 126.58 | 3.85 | 61728 | 1.000 | |
| 250 | 162.85 | 35.917 | 9.442 | 0.771 | 156.25 | 1.37 | 33445 | 0.999 | |
| 300 | 195.45 | 40.290 | 6.448 | 0.976 | 181.82 | 1.39 | 46083 | 1.000 | |
| 400 | 250.30 | 74.405 | 3.685 | 0.882 | 212.77 | 0.93 | 42017 | 0.997 | |
| 2.0 | 100 | 50.00 | 1.863 | 5.067 | 0.429 | 49.02 | 50.75 | 121951 | 1.000 |
| 150 | 75.00 | 8.350 | 16.582 | 0.745 | 75.76 | 4.92 | 28249 | 1.000 | |
| 200 | 100.00 | 12.151 | 9.673 | 0.887 | 98.04 | 4.03 | 38760 | 0.999 | |
| 250 | 125.00 | 20.768 | 5.988 | 0.768 | 117.65 | 3.23 | 44643 | 1.000 | |
| 300 | 149.61 | 32.689 | 10.594 | 0.989 | 147.06 | 1.32 | 28653 | 0.999 | |
| 400 | 196.86 | 35.678 | 4.836 | 0.952 | 181.82 | 1.72 | 56818 | 0.999 | |
| 2.5 | 100 | 40.00 | 2.152 | 8.061 | 0.870 | 39.53 | 26.56 | 41494 | 1.000 |
| 150 | 60.00 | 2.826 | 9.903 | 0.758 | 59.52 | 20.02 | 70922 | 1.000 | |
| 200 | 80.00 | 4.250 | 6.679 | 0.883 | 78.74 | 15.36 | 95238 | 1.000 | |
| 250 | 100.00 | 7.976 | 9.442 | 0.943 | 99.01 | 6.54 | 64103 | 1.000 | |
| 300 | 120.00 | 14.348 | 8.982 | 0.833 | 117.65 | 3.39 | 46948 | 0.999 | |
| 400 | 159.06 | 18.243 | 6.218 | 0.642 | 153.85 | 3.55 | 84034 | 1.000 | |
| 3.0 | 100 | 33.33 | 1.166 | 7.600 | 0.620 | 33.00 | 43.93 | 47847 | 1.000 |
| 150 | 50.00 | 2.288 | 11.976 | 0.873 | 49.75 | 22.83 | 56497 | 1.000 | |
| 200 | 66.67 | 2.958 | 12.206 | 0.946 | 66.67 | 17.18 | 76336 | 1.000 | |
| 250 | 83.33 | 5.757 | 13.818 | 0.967 | 83.33 | 8.28 | 57471 | 1.000 | |
| 300 | 100.00 | 5.313 | 10.594 | 0.949 | 99.01 | 9.72 | 95238 | 1.000 | |
| 400 | 133.33 | 17.811 | 8.751 | 0.955 | 129.87 | 2.84 | 47847 | 1.000 | |