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. 2022 Jul 26;29(60):91036–91060. doi: 10.1007/s11356-022-21957-6

Table 2.

Kinetic parameters of adsorption of Cr6+ ions to the activated TETA-PP

Parameter PFO PSO
Activated TETA-PP (g/L) Cr6+ conc. (mg/L) qe (exp.) qe (calc.) k1 × 103 R2 qe (calc.) k2 × 103 h R2
1.0 100 99.45 39.500 13.588 0.974 100.00 0.92 9225 0.997
150 147.33 39.537 5.527 0.761 131.58 1.68 29070 1.000
200 188.70 56.403 3.224 0.576 156.25 1.50 36630 0.996
250 229.76 70.648 5.067 0.976 200.00 0.79 31447 0.998
300 246.34 65.268 3.685 0.989 212.77 1.18 53476 1.000
400 326.56 78.886 3.455 0.926 285.71 1.03 84034 1.000
1.5 100 66.67 4.300 8.291 0.767 65.79 14.72 63694 1.000
150 100.00 27.791 14.739 0.896 101.01 1.45 14793 0.999
200 132.65 16.665 5.988 0.905 126.58 3.85 61728 1.000
250 162.85 35.917 9.442 0.771 156.25 1.37 33445 0.999
300 195.45 40.290 6.448 0.976 181.82 1.39 46083 1.000
400 250.30 74.405 3.685 0.882 212.77 0.93 42017 0.997
2.0 100 50.00 1.863 5.067 0.429 49.02 50.75 121951 1.000
150 75.00 8.350 16.582 0.745 75.76 4.92 28249 1.000
200 100.00 12.151 9.673 0.887 98.04 4.03 38760 0.999
250 125.00 20.768 5.988 0.768 117.65 3.23 44643 1.000
300 149.61 32.689 10.594 0.989 147.06 1.32 28653 0.999
400 196.86 35.678 4.836 0.952 181.82 1.72 56818 0.999
2.5 100 40.00 2.152 8.061 0.870 39.53 26.56 41494 1.000
150 60.00 2.826 9.903 0.758 59.52 20.02 70922 1.000
200 80.00 4.250 6.679 0.883 78.74 15.36 95238 1.000
250 100.00 7.976 9.442 0.943 99.01 6.54 64103 1.000
300 120.00 14.348 8.982 0.833 117.65 3.39 46948 0.999
400 159.06 18.243 6.218 0.642 153.85 3.55 84034 1.000
3.0 100 33.33 1.166 7.600 0.620 33.00 43.93 47847 1.000
150 50.00 2.288 11.976 0.873 49.75 22.83 56497 1.000
200 66.67 2.958 12.206 0.946 66.67 17.18 76336 1.000
250 83.33 5.757 13.818 0.967 83.33 8.28 57471 1.000
300 100.00 5.313 10.594 0.949 99.01 9.72 95238 1.000
400 133.33 17.811 8.751 0.955 129.87 2.84 47847 1.000