Table 3.
Kinetic parameters of adsorption of Cr6+ ions to activated TETA-PP
| Sorbent dose (g/L) | Cr6+ conc. (mg/L) | ELH | IPD | ||||
|---|---|---|---|---|---|---|---|
| β | α | R2 | Kdif | C | R2 | ||
| 1.0 | 100 | 0.084 | 2.03 × 102 | 0.9801 | 3.213 | 56.017 | 0.9761 |
| 150 | 0.088 | 7.55 × 103 | 0.8889 | 2.861 | 96.524 | 0.7738 | |
| 200 | 0.105 | 5.26 × 105 | 0.6686 | 2.477 | 122.980 | 0.6142 | |
| 250 | 0.073 | 1.23 × 105 | 0.8977 | 3.819 | 148.630 | 0.9617 | |
| 300 | 0.085 | 3.57 × 106 | 0.9731 | 3.164 | 170.450 | 0.9643 | |
| 400 | 0.075 | 1.05 × 108 | 0.9392 | 3.604 | 235.600 | 0.9459 | |
| 1.5 | 100 | 0.606 | 2.03 × 1015 | 0.8785 | 0.413 | 60.713 | 0.7511 |
| 150 | 0.097 | 9.10 × 102 | 0.9488 | 2.696 | 66.223 | 0.8854 | |
| 200 | 0.235 | 1.74 × 1011 | 0.9653 | 1.122 | 112.350 | 0.9144 | |
| 250 | 0.069 | 4.65 × 103 | 0.8455 | 3.617 | 113.060 | 0.7205 | |
| 300 | 0.098 | 2.91 × 106 | 0.9877 | 2.750 | 147.090 | 0.9836 | |
| 400 | 0.086 | 3.41 × 106 | 0.8179 | 3.243 | 166.250 | 0.8799 | |
| 2.0 | 100 | 1.415 | 9.24 × 1027 | 0.6281 | 0.167 | 47.261 | 0.4810 |
| 150 | 0.179 | 3.21 × 104 | 0.6822 | 1.338 | 60.125 | 0.5362 | |
| 200 | 0.282 | 1.68 × 1010 | 0.8863 | 0.941 | 85.762 | 0.8533 | |
| 250 | 0.159 | 5.13 × 106 | 0.8626 | 1.577 | 98.043 | 0.7460 | |
| 300 | 0.105 | 1.83 × 105 | 0.9443 | 2.614 | 111.750 | 0.9678 | |
| 400 | 0.147 | 9.83 × 109 | 0.8916 | 1.905 | 155.950 | 0.9530 | |
| 2.5 | 100 | 1.532 | 6.37 × 1023 | 0.9015 | 0.170 | 37.336 | 0.8319 |
| 150 | 0.863 | 1.56 × 1020 | 0.8626 | 0.293 | 56.042 | 0.7526 | |
| 200 | 0.811 | 3.53 × 1025 | 0.9592 | 0.320 | 74.660 | 0.8847 | |
| 250 | 0.406 | 3.19 × 1015 | 0.9489 | 0.657 | 90.277 | 0.9258 | |
| 300 | 0.297 | 1.67 × 103 | 0.8537 | 0.937 | 104.360 | 0.9057 | |
| 400 | 0.161 | 1.86 × 109 | 0.7282 | 1.534 | 134.250 | 0.6051 | |
| 3.0 | 100 | 5.079 | 2.89 × 1069 | 0.5121 | 0.059 | 32.135 | 0.6225 |
| 150 | 1.173 | 1.19 × 1023 | 0.9001 | 0.221 | 47.092 | 0.8249 | |
| 200 | 1.109 | 4.35 × 1029 | 0.9635 | 0.243 | 63.294 | 0.9578 | |
| 250 | 0.629 | 3.31 × 1020 | 0.9421 | 0.439 | 77.286 | 0.9830 | |
| 300 | 0.628 | 9.60 × 1024 | 0.9544 | 0.4283 | 93.801 | 0.9458 | |
| 400 | 0.203 | 6.02 × 109 | 0.9516 | 1.3383 | 112.35 | 0.9585 | |