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. 2022 Dec 7;12(54):34850–34873. doi: 10.1039/d2ra06734j

Input optimization parameters of the TCO, ETL, and absorber layer of the study.

Parameters ITO TiO2 PCBM ZnO C60 IGZO SnO2 WS2 CeO2 Cs2BiAgI6
Thickness (nm) 500 30 50 50 50 30 100 100 100 800a
Band gap, Eg (eV) 3.5 3.2 2 3.3 1.7 3.05 3.6 1.8 3.5 1.6
Electron affinity, X (eV) 4 4 3.9 4 3.9 4.16 4 3.95 4.6 3.90
Dielectric permittivity (relative), εr 9 9 3.9 9 4.2 10 9 13.6 9 6.5
CB effective density of states, NC (1/cm3) 2.2 × 1018 2 × 1018 2.5 × 1021 3.7 × 1018 8.0 × 1019 5 × 1018 2.2 × 1018 1 × 1018 1 × 1020 1 × 1019
VB effective density of states, NV (1/cm3) 1.8 × 1019 1.8 × 1019 2.5 × 1021 1.8 × 1019 8.0 × 1019 5 × 1018 1.8 × 1019 2.4 × 1019 2 × 1021 1 × 1019
Electron mobility, μn (cm2 V−1 s−1) 20 20 0.2 100 8.0 × 10−2 15 100 100 100 2
Hole mobility, μh (cm2 V−1 s−1) 10 10 0.2 25 3.5 × 10−3 0.1 25 100 25 2
Shallow uniform acceptor density, NA (1/cm3) 0 0 0 0 0 0 0 0 0 1 × 1015a
Shallow uniform donor density, ND (1/cm3) 1 × 1021 9 × 1016 2.93 × 1017 1 × 1018 1 × 1017 1 × 1017 1 × 1017 1 × 1018 1021 0a
Defect density, Nt (1/cm3) 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a 1 × 1015a
Reference 14 14 14 14 14 14 14 14 14 72
a

This study.