Table 1. Experimental details.
| Crystal data | |
| Chemical formula | [Pt2Cl4(NH3)2{μ-HN=C(O)Bu t }2] |
| M r | 766.33 |
| Crystal system, space group | Monoclinic, C2/c |
| Temperature (K) | 293 |
| a, b, c (Å) | 19.3247 (3), 8.8795 (1), 12.7062 (2) |
| β (°) | 108.332 (1) |
| V (Å3) | 2069.65 (5) |
| Z | 4 |
| Radiation type | Mo Kα |
| μ (mm−1) | 14.03 |
| Crystal size (mm) | 0.77 × 0.24 × 0.21 |
| Data collection | |
| Diffractometer | Nonius KappaCCD |
| Absorption correction | Multi-scan (SADABS) |
| T min, T max | 0.03, 0.05 |
| No. of measured, independent and observed [I > 2.0σ(I)] reflections | 29306, 6496, 4944 |
| R int | 0.027 |
| (sin θ/λ)max (Å−1) | 0.910 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.022, 0.017, 1.12 |
| No. of reflections | 4707 |
| No. of parameters | 100 |
| H-atom treatment | H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) | 1.30, −1.30 |