Table 6. Kinetic Study Model Fitting Parameters of MMO/MG and MMO/CTX/MG Samples.
model | equation | parameters | MMO + MG | MMO/CTX + MG |
---|---|---|---|---|
pseudo-first order | qt = qe (1 – e–K1t), qe is the adsorption capacity at equilibrium and K1 is the pseudo-first-order rate constant | K1 (min–1) | 18.65 × 104 | 18.64 × 104 |
qe (mg/g) | 9.22 | 8.9 | ||
R2 | 0.86 | 0.96 | ||
pseudo-second order | K2 is the pseudo-second-order rate constant | K2 (g/(mg min)) | 1.03 × 106 | 1.03 × 106 |
qe (mg/g) | 9.22 | 8.9 | ||
R2 | 0.83 | 0.96 | ||
intraparticle diffusion | Kip is the measure of diffusion coefficient and Cip is the intraparticle diffusion constant | Kip (mg/g min0.5) | 0.69 | 0.64 |
Cip (mg/g) | 5.07 | 4.71 | ||
R2 | 0.8 | 0.57 | ||
mixed first and second order | f2 is the mixed 1,2 order coefficient and K is the adsorption rate constant | K (min–1) | 12.82 × 10–4 | 13.15 × 10–4 |
qe (mg/g) | 11.46 | 9.82 | ||
f2 (g/(mg min)) | 0.99 | 0.99 | ||
R2 | 0.97 | 0.99 | ||
Avrami model | qt = qe (1 – [e–Kavt]nav), Kav is the Avrami rate constant and nav is the Avrami component | Kav (min–1) | 10.63 | 9.3 |
nav (−) | 0.44 | 0.68 | ||
qe (mg/g) | 0.41 | 0.65 | ||
R2 | 0.96 | 0.98 |