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. 2022 Nov 17;7(48):44103–44115. doi: 10.1021/acsomega.2c05528

Table 6. Kinetic Study Model Fitting Parameters of MMO/MG and MMO/CTX/MG Samples.

model equation parameters MMO + MG MMO/CTX + MG
pseudo-first order qt = qe (1 – eK1t), qe is the adsorption capacity at equilibrium and K1 is the pseudo-first-order rate constant K1 (min–1) 18.65 × 104 18.64 × 104
qe (mg/g) 9.22 8.9
R2 0.86 0.96
pseudo-second order Inline graphicK2 is the pseudo-second-order rate constant K2 (g/(mg min)) 1.03 × 106 1.03 × 106
qe (mg/g) 9.22 8.9
R2 0.83 0.96
intraparticle diffusion Inline graphicKip is the measure of diffusion coefficient and Cip is the intraparticle diffusion constant Kip (mg/g min0.5) 0.69 0.64
Cip (mg/g) 5.07 4.71
R2 0.8 0.57
mixed first and second order Inline graphicf2 is the mixed 1,2 order coefficient and K is the adsorption rate constant K (min–1) 12.82 × 10–4 13.15 × 10–4
qe (mg/g) 11.46 9.82
f2 (g/(mg min)) 0.99 0.99
R2 0.97 0.99
Avrami model qt = qe (1 – [eKavt]nav), Kav is the Avrami rate constant and nav is the Avrami component Kav (min–1) 10.63 9.3
nav (−) 0.44 0.68
qe (mg/g) 0.41 0.65
R2 0.96 0.98