Table 2.
Selected 1H NMR chemical shifts (in ppm) for pyrroles 3a–c and 8a–c.
| Position | 3a | 3b | 3c | 8a | 8b | 8c |
|---|---|---|---|---|---|---|
| 3 | 4.59 | 4.60 | 4.60 | 4.60 | 4.60 | 4.59 |
| 6 | 5.36 | 5.39 | 5.40 | 5.36 | 5.36 | 5.36 |
| 16 | - | - | - | 4.97 | 4.98 | 4.95 |
| 18 | 0.91 | 0.87 | 0.88 | 0.90 | 0.95 | 0.90 |
| 19 | 1.07 | 1.07 | 1.08 | 1.02 | 1.04 | 1.03 |
| 20 | - | - | - | 2.99 | 3.06 | 3.05 |
| 21 | 1.98 | 1.95 | 1.96 | 0.84 | 1.22 | 1.23 |
| 23, 24 | - | - | - | 5.85 | 5.78 | 5.75 |
| 26 | 3.82, 3.77 |
3.94 | 3.98, 3.93 |
2.09 | 2.20 | 2.18 |
| 27 | 0.84 | 0.98 | 1.00 | - | - | - |
All NMR spectra were acquired in CDCl3 from a 600 MHz NMR spectrometer.