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. 2022 Nov 25;27(23):8218. doi: 10.3390/molecules27238218

Table 1.

Mossbauer parameters for selected [2Fe-2S]2+ and [2Fe-2S]+ proteins.

System Cluster Type Formal Valences Fe Ligands Stot δ (mm/s) |ΔEQ| (mm/s) Refs.
FdI A . aeolicus [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.27 0.60 [70]
putidaredoxin P. putida [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.27 0.60 [69]
yeast Grx3 [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.29 0.55–0.76 [73]
human ISCA1 [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.28 0.50 [74]
human ISCA2 [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.27 0.53 [74]
anamorsin (site 1) [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.26 0.57 [55]
anamorsin (site 2) [2Fe-2S]2+ 2 Fe3+ 4 Cys 0 0.28 0.39 [55]
Rieske thermus thermophilus [2Fe-2S]2+ Fe3+
Fe3+
2 Cys
2 His
0 0.24
0.32
0.32
0.91
[66]
mitoNEET [2Fe-2S]2+ Fe3+
Fe3+
2 Cys
1 Cys 1 His
0 0.26
0.30
0.47
0.96
[18,41]
E. coli IscU [2Fe-2S]2+ Fe3+
Fe3+
2 Cys
1 Cys 1 His
0 0.27
0.32
0.66
0.94
[68]
E. coli IscR [2Fe-2S]2+ Fe3+
Fe3+
2 Cys
1 Cys 1 His
0 0.27
0.30
0.48
0.72
[67]
yeast Fra2-Grx3 [2Fe-2S]2+ Fe3+
Fe3+
2 Cys
1 Cys 1 His
0 0.30
0.32
0.50
0.82
[73]
FdI A. aeolicus [2Fe-2S]1+ Fe3+
Fe2+
2 Cys
2 Cys
1/2 0.30
0.62
1.0
3.0
[70]
putidaredoxin P. putida [2Fe-2S]1+ Fe3+
Fe2+
2 Cys
2 Cys
1/2 0.35
0.60
0.65
2.70
[69]
anamorsin (site 1) [2Fe-2S]1+ 2 Fe2.5+ 4 Cys 1/2 0.26 0.57 [55]
anamorsin (site 2) [2Fe-2S]1+ 2 Fe2.5+ 4 Cys 1/2 0.28 0.39 [55]
Rieske thermus thermophilus [2Fe-2S]1+ Fe3+
Fe2+
2 Cys
2 His
1/2 0.31
0.74
0.63
3.05
[66]
E. coli IscR [2Fe-2S]1+ Fe3+
Fe2+
2 Cys
1 Cys 1 His
1/2 0.33
0.70
1.09
3.4
[67]
mitoNEET [2Fe-2S]1+ Fe3+
Fe2+
2 Cys
1 Cys, 1 His
1/2 0.32
0.68
1.07
3.15
[41]