Table 2.
1H NMR (400 MHz, CDCl3) and 13C NMR (100 MHz, CDCl3) data for compound 4
| 4 | ||||
|---|---|---|---|---|
| Pos. | δC | type | δH | mult (J in Hz) |
| 1 | 202.3 | C | ||
| 2 | 50.5 | CH2 | 2.88 | ddd (2.1, 4.8, 13.0) |
| 2.44 | dd (11.6, 13.0) | |||
| 3 | 67.9 | CH | 4.02 | m |
| 4 | 42.6 | CH2 | 2.32 | m |
| 1.60 | m | |||
| 5 | 31.0 | CH | 2.08 | m |
| 6 | 61.1 | CH | 2.95 | d (12.2) |
| 7 | 20.5 | CH3 | 1.12 | d (6.4) |
| 8 | 156.9 | C | ||
| 9 | 112.4 | CH | 6.09 | s |
| 10 | 141.7 | C | ||
| 11 | 107.7 | CH | 5.53 | d (1.1) |
| 12 | 192.9 | C | ||
| 13 | 83.9 | C | ||
| 14 | 193.0 | C | ||
| 15 | 115.3 | C | ||
| 16 | 153.7 | CH | 7.84 | d (1.1) |
| 17 | 22.0 | CH3 | 1.54 | s |
| 1′ | 176.4 | C | ||
| 2′ | 36.2 | CH | 2.70 | m |
| 3′ | 40.8 | CH2 | 1.77 | m |
| 1.13 | m | |||
| 4′ | 31.8 | CH | 1.52 | m |
| 5′ | 29.5 | CH2 | 1.34 | m |
| 1.15 | m | |||
| 6′ | 11.1 | CH3 | 0.89 | t (7.4) |
| 7′ | 17.6 | CH3 | 1.19 | d (7.0) |
| 8′ | 19.1 | CH3 | 0.92 | d (6.6) |