Full crystal data and structure refinement parameters.
| Complex | 1 | 2 |
| Formula | C44H46Cd4N6O12S2 | C42H42Cd4N6O12S2 |
| Formula weight | 1364.63 | 1336.58 |
| Temperature (K) | 293(2) | 293(2) |
| Crystal system | Orthorhombic | Orthorhombic |
| Space group | Pbcn | Pbcn |
| a (Å) | 20.758(6) | 20.758(6) |
| b (Å) | 11.022(3) | 11.022(3) |
| c (Å) | 21.396(6) | 21.396(6) |
| V [Å]3 | 4895(2) | 4895(2) |
| Z | 4 | 4 |
| d cal (g cm−3) | 1.852 | 1.814 |
| μ (mm−1) | 1.865 | 1.863 |
| F (000) | 2688 | 2624 |
| Total reflection | 182 284 | 182 284 |
| Unique reflections | 5095 | 5095 |
| Observed data [I > 2σ(I)] | 3924 | 3924 |
| R(int) | 0.082 | 0.08 |
| Goodness-of-fit on F2 | 1.18 | 1.20 |
| Min. and max. resd. dens. [e/Å3] | −1.43, 1.00 | −1.55, 0.74 |
| R 1, wR2 (all data) | 0.0881, 0.1482 | 0.0891, 0.1518 |
| R 1, wR2 [I > 2σ(I)] | 0.0672, 0.1368 | 0.0680, 0.1402 |