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. 2022 Nov 28;55(23):10723–10736. doi: 10.1021/acs.macromol.2c01264

Figure 7.

Figure 7

Bond-vector orientation correlation function, c(z) (eq 25), as a function of the number of entanglements z = Inline graphic/Le along the chain. Lines of equal color are for the same chain stiffness (see legend), full colors are for the longest rings (N = 640), while lines in fainter colors are for chains of shorter contour lengths (see arrow’s direction). The long-dashed lines correspond to the exponential decay typical of linear polymers with local stiffness, namely, Inline graphic, where the values for ⟨ cos θ⟩ring are reported in Table 1. The short-dashed line is the analytical function for an exactly double-folded polymer filament of contour length = 2Le (see the text for details).