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. 2022 Dec 2;144(49):22528–22539. doi: 10.1021/jacs.2c07522

Figure 3.

Figure 3

(a) Collision energy vs arrival time distribution heat map for [PhCd + Na]+ (m/z = 2481, top) and [AmNi + Na]+ (m/z = 2599, bottom) as well as the corresponding fragments. 10 μM PhCd and AmNi were used in 500 μM NaI and 4:1 toluene/methanol (PhCd) or 7:3 methanol/DCM (AmNi). The intact thread cation TAm+ was observed, whereas no TPh+ ions could be detected (Figure S31). (b) CCSN2 distributions of [PhCd + Na]+ and its fragments (4, 5) at Elab = 90 eV (top) as well as [AmNi + Na]+ and its fragments (6, 7) at Elab = 120 eV (bottom).