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. 2021 May 13;417:126108. doi: 10.1016/j.jhazmat.2021.126108

Table 3.

Comprehensive evaluation of the various technologies in converting plastic waste to fuels.

Technologies Function Conditions
Chemo-lysis Depolymerise plastic into its monomer through various Methanolysis:
depolymerisation routes: methanolysis, glycolysis, hydrolysis, ammonolysis and hydrogenation Temperature: 180–280 °C
Pressure: 20–40 atm
Hydrolysis: the reaction of plastic with water under neutral, acidic or basic conditions at high temperature and pressure
Glycolysis:
Temperature: 180–250 °C
With excess of glycol
Pyrolysis Break down macrostructure of the polymer to form smaller molecules by depolymerisation or random fragmentation. The pyrolysis products of plastic waste can be in the forms of gas, liquid and solid residue. Temperature: 500 °C
Pressure: 1–2 atm
Fluid catalytic cracking Convert plastic waste into fuel, commodity chemicals and fine chemicals through thermal and catalytic decomposition process. Temperature: 300–350 °C
Hydrogen technologies Convert plastic waste into liquid fuel through hydrocracking reactions. Temperature: 375–400 °C
Pressure: 70 atm
With the addition of hydrogen gas
KDV process Catalytic depolymerisation conversion of biomass and plastic waste into liquid fuels such as diesel oil. Temperature: 250–320 °C
Pressure: Atmospheric pressure
Gasification Converts plastic waste to a gaseous mixture containing CO2, CO, H2, CH4 and other light hydrocarbons via partial oxidation. The gaseous mixture is known as syngas. Temperature: 1200–1500 °C
Pressure: 50–100 atm
With oxygen and steam