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. 2022 Nov 15;5(1):208–219. doi: 10.1039/d2na00544a

Selected Mössbauer fit parameters for the H-rich heteropolymer ferritina.

T (K) Site δ (mm s−1) ΔEq (mm s−1) H hf (kOe) Area (%) Core or shell
300 1 0.36 0.57 0 59 Core
2 0.36 0.99 0 41 Shell
15 1 0.48 0.54 0 19.4 Core
2 0.48 1.25 0 11.6 Shell
3 0.48 0 484.2 46.9 Core
4 0.48 0 434.2 22.2 Shell
4.2 3 0.50 0 488.2 59.5 Core
4 0.45 0 446.0 40.5 Shell
a

Sites 1 and 2 are associated with quadrupolar spectra (green and purple traces in Fig. 7). The reported parameters correspond to the average values of fitted quadrupole distributions. Sites 3 and 4 are associated with magnetic hyperfine spectra (blue and red traces in Fig. 7). The reported parameters correspond to the average values of fitted hyperfine field distributions. Estimated uncertainties: δ (±0.02 mm s−1), ΔEq (±0.04 mm s−1), Hhf (±2 kOe), area (±3%).