Equilibrium and rate constants for the dissociation of 3-(hydroxybenzyl)triazolium adducts^a.

Entry	Triazolium salt	Tetrahedral adduct	k d (×10−5 s−1)	k d fit (×10−5 s−1)	k a (×10−2 M−1 s−1)	k a fit (×10−2 M−1 s−1)	K diss (×10−5 M−1)	K fit (×10−5 M−1)	1/Kdiss (×102 M−1)
1	39	12	4.54	4.06	20.7	16.6	21.9	24.5	45.7
2	42	18	0.882	0.879	41.8	43.5	2.11	2.02	474
3	45	29	25.6	26.1	23.3	24.8	11.0	10.5	9.09
4	46	30	8.46	8.57	135	136	6.27	6.30	160

^aConditions: tetrahedral adduct 20 mM, Et₃N : Et₃N·HCl (2 : 1) 90 mM in CD₃OD at 25 °C.