Table 2. Data from the Catalytic Oxidation of Glycerol by the Pt/M@NPCN Catalystsa.
| selectivity
(%) |
||||||
|---|---|---|---|---|---|---|
| catalyst | conv. (%) | OA | LA | GLYA | DHA | TA |
| Pt/Ni@NPCNs | 70.10 | 1.10 | 10.00 | 63.30 | 20.40 | 5.10 |
| Pt/Zr@NPCNs | 63.10 | - | 4.30 | 81.60 | 14.10 | - |
| Pt/Mn@NPCNs | 13.30 | 4.70 | 28.10 | 48.40 | 18.80 | - |
| Pt/Ce@NPCNs | 12.70 | - | 3.10 | 71.30 | 25.30 | - |
| Pt/Zn@NPCNs | 0.40 | 1.30 | 22.40 | 26.30 | 50.00 | - |
| Pt/Cu@NPCNs | - | - | - | - | - | - |
| Pt/Fe@NPCNs | - | - | - | - | - | - |
Reaction conditions: glycerol in water (0.3 M, 20 mL), glycerol: Pt = 500:1 mol mol–1, 333 K, 6 h, P(O2) = 10 bar.