Table 2. EPR Parameters Used for Simulations of the WV Signalsa.
| g1 | g2 | g3 | g-anisotropy | g-rhombicity | |
|---|---|---|---|---|---|
| WDV | 1.993 (0.009) | 1.909 (0.005) | 1.852 (0.007) | 0.141 | 0.59 |
| WFV | 1.995 (0.010) | 1.881 (0.006) | 1.852 (0.007) | 0.143 | 0.79 |
| 183W hyperfine parameters | A1 | A2 | A3 | ||
| 183WD | 225 (20) | 112(10) | 123 (10) | ||
| 183WF | 225 (20) | 129(5) | 134 (5) |
Spectral broadening was described by the g-strain effect (parameters in brackets). Anisotropy (g1–g3) and rhombicity [(g1 – g2)/(g1 – g3)] were also calculated. The natural abundance of the isotope 183W (I = 1/2) was considered (14.3%), and hyperfine coupling parameters are given in MHz.