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. 2022 Dec 23;13(1):638–651. doi: 10.1039/d2ra06708k

Results of NH3-TPD and H2-TPR for fresh and aged samples.

Samples Desorbed NH3a(mmol g−1 catalyst) Total H2b consumption
Peak α Peak β Peak γ (mmol g−1 catalyst)
Cu-SAPO-34 0.28 0.12 0.19 1.86
Fe-MOR 0.09 0.25 0.69
Cu-SAPO-34@Fe-MOR 0.08 0.24 0.07 2.03
Cu-SAPO-34-750 0.23 0.15 0.16 1.05
Fe-MOR-750 0.23 0.18
Cu-SAPO-34@Fe-MOR-750 0.45 0.09 0.06 1.51
a

The α, β and γ peaks respectively correspond to the weak, medium and strong acid sites, and are estimated from NH3-TPD data of the deconvoluted peaks.

b

The total H2c consumption calculated from H2-TPR data.