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. 2022 Dec 23;13(1):674–687. doi: 10.1039/d2ra07077d

Comparison of the catalytic activity of PMA@MIL-53 (Fe) in the nitration of phenol with other reported catalyst systems in the literature.

Entry Catalyst Time (min) Yield (%) Ref
Total Ortho Para
1 Montmorillonite KSF 60 84 44 40 81
2 Tetrabutylammonium chromate 2880 80 44 36 82
3 [KHSO4·2KHSO5·K2SO4] 180 79 40 39 83
4 Cerium(iv) ammonium nitrate (CAN) 1440 69 28 41 84
5 Silica sulfuric acid 25 79 36 43 85
6 PMA@MIL-53 (Fe) 15 99.99 54.98 45.01 This work