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. 2022 Feb 18;66(21):2101090. doi: 10.1002/mnfr.202101090

Table 2.

Gut microbiota catabolites identified after 5 and 24 h faecal fermentation of monomeric and oligomeric flavan‐3‐ols

Molecular weight (Da) Gut microbiota catabolites
Fission catabolites of oligomers
Dimers
Derived from catabolic pathway of dimer A2
578 1 fission dimer A2, form 1
Derived from catabolic pathway of dimer B2
580 1 fission dimer B2, form 1
582 2 fission dimer B2, form 1
Trimers
Derived from catabolic pathway of trimer AA
864 1 fission trimer AA, form 1
864 1 fission trimer AA, form 2
Derived from catabolic pathway of trimer AB
866 1 fission trimer AB, form 1
866 1 fission trimer AB, form 2
Derived from catabolic pathway of trimer BB
868 1 fission trimer BB, form 1
870 2 fission trimer BB, form 1
Tetramers
Derived from catabolic pathway of tetramer BBB
1156 1 fission tetramer BBB, form 1
1156 1 fission tetramer BBB, form 2
1156 1 fission tetramer BBB, form 3
1158 2 fission tetramer BBB, form 1
1160 3 fission tetramer BBB, form 1
1162 4 fission tetramer BBB, form 1
Diphenylpropan‐2‐ols
276 1‐(Hydroxyphenyl)‐3‐(2″,4″,6″‐trihydroxyphenyl)‐propan‐2‐ol
292 1‐(3′,5′‐Dihydroxyphenyl)‐3‐(2″,4″,6″‐trihydroxyphenyl)‐propan‐2‐ol
292 1‐(3′,4′‐Dihydroxyphenyl)‐3‐(2″,4″,6″‐trihydroxyphenyl)‐propan‐2‐ol
Phenyl‐γ‐valerolactones
192 5‐(4′‐Hydroxyphenyl)‐γ‐valerolactone
192 5‐(3′‐Hydroxyphenyl)‐γ‐valerolactone
208 5‐(3′,5′‐Dihydroxyphenyl)‐γ‐valerolactone
208 5‐(3′,4′‐Dihydroxyphenyl)‐γ‐valerolactone
Phenylvaleric acids
194 5‐(3′‐Hydroxyphenyl)valeric acid
210 4‐Hydroxy‐5‐(hydroxyphenyl)valeric acid
210 5‐(3′,5′‐Dihydroxyphenyl)valeric acid
210 5‐(3′,4′‐Dihydroxyphenyl)valeric acid
Phenylpropanoic acids
166 3‐(3′‐Hydroxyphenyl)propanoic acid
182 3‐(3′,5′‐Dihydroxyphenyl)propanoic acid
Benzoic acid
170 3,4,5‐Trihydroxybenzoic acid
Benzene derivative
126 Benzene‐1,2,3‐triol
Monomer unit
290 (−)‐Epicatechin
Dimer unit
564 Theaflavin

The nomenclature of catabolites was standardized according to Kay et al.[60] Chromatographic and spectrometric information is provided in Table S2, Supporting Information. Structures of fission derivatives of dimer A2 and dimer B2 are reported in Figures S2 and S3, Supporting Information.