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. 2022 Dec 9;27(24):8725. doi: 10.3390/molecules27248725

Table 1.

Spectral properties of the investigated compounds in different solvents (dielectric constant, ε, and refractive index, n) absorption maximum (λabs), emission maximum (λem), Stokes shift (Δν˜). Bold values refer to the main absorption or emission maxima.

DMA-QP DMA-QF DMA-QT
Solvent f (ε, n) a λabs/nm λem/nm Δν˜/cm1 λabs/nm λem/nm Δν˜/cm1 λabs/nm λem/nm Δν˜/cm1
Tol 0.02423 368 430 3920 428 484 2700 438, 462 sh 488, 523 1200
Tol/An
(50/50 v/v)
0.14278 367 437 4365 433 504 3250 440, 462 sh 496, 528 1480
An 0.22353 371 448 4630 435 523 3570 442, 462 sh 504, 533 1800
EtOAc 0.36011 363 443 4975 431 527 4230 430, 455 sh 496 sh, 521 1820
An/DCE
(50/50 v/v)
0.39998 369 452 4980 436 540 4420 440, 462 sh 504, 533 1800
DCE 0.4968 368 458 5340 437 545 4540 437, 462 sh 513 sh, 532 2850
DCE/DMF
(50/50 v/v)
0.58324 368 468 5810 437 568 5280 438, 462 sh 536 2990
EtOH 0.6668 367 480 6415 452 612 5780 429, 455 sh 522 2820
AcCN 0.66697 364 451 5300 431 581 5990 432,455 sh 537 3360
DMF 0.71215 368 474 6080 437 579 5610 440, 462 sh 548 3400

a f(ε,n)=(ε1ε+2n21n2+2); sh = shoulder.