Table 4.

Constituents of AE from run V1 as determined by LC‐DAD‐MS ⁿ analysis

Constituent	Retention time (min)	[M + H]−	MS2	MS3	Concentration (mg g−1)	Reference
Flavonoids
Apigenin 6,8‐di‐C‐glucoside a	8.6	593	503 473 383 353	383 353	5.99 ± 0.08	30
Luteolin di‐C‐hexoside	9.2	609	489 429 357 327	299 284	6.94 ± 0.06	31
Luteolin C‐(hexoside‐O‐rhamnoside)	9.6	593	473 429 357 327	299 284	4.61 ± 0.05	31
Vitexin‐2″‐O‐glucoside a	9.7	593	473 413 293	293	7.22 ± 0.07	32
Apigenin C‐(hexoside‐O‐rhamnoside)	10.1	577	457 413 293	293	1.72 ± 0.02	31
Eriodictyol‐7‐O‐glucoside a	10.6	449	269	251 225 209	3.77 ± 0.02	33
Luteolin‐7‐O‐glucuronide a	10.9	461	285 381 357 327	241 217 199 175 151	31.10 ± 0.10	31
Apigenin glucuronide	11.9	445	269	225 183 151	15.43 ± 0.08	31
O‐Methyl luteolin glucuronide	12.4	475	299	284	0.62 ± 0.01	31
Total					78.38
Other phenolics
(−)‐Gallocatechin	1.7	305	175	147 131	2.70 ± 0.03	34
Caffeoyl‐O‐hexoside	1.8	341	179 161 143		2.72 ± 0.04	34
Protocatecuic acid hexoside	6.1	315	153	109	0.79 ± 0.01	35
Unidentified	12.2	551	389 371 345 327	327 317 301	2.67 ± 0.02
Total					8.87
Organic acids
Citric acid a	2.5	191	173 111	67	2.15 ± 0.03
Cannabinoids
Cannabidiol a	28.3	315	259 233 193 135 123	231 217 189 161	0.85 ± 0.01

^a Indicates identification with reference standards.