Table 2.
The13C NMR (150 MHz) data in DMSO-d6 for metabolites 1 and 3−8. (δ in ppm).
| No. | 1 | 3 | 4 | 5 | 6 | 7 | 8 |
|---|---|---|---|---|---|---|---|
| 1 | 171.9 | 171.9 | 171.9 | 171.2 | 171.9 | 171.2 | 171.5 |
| 2 | 35.4 | 35.3 | 35.3 | 31.1 | 35.4 | 31.1 | 34.9 |
| 3 | 25.4 | 25.3 | 25.3 | 29.5 | 25.3 | 29.6 | 21.1 |
| 4 | 28.8 | 28.7 | 28.6 | 73.5 | 28.6 | 73.1 | 33.0 |
| 5 | 29.2 | 28.6 | 28.5 | 31.2 | 29.0 | 33.5 | 74.8 |
| 6 | 26.4 | 26.6 | 26.5 | 33.8 | 26.1 | 22.4 | 31.2 |
| 7 | 32.9 | 33.2 | 33.2 | 27.3 | 32.6 | 38.1 | 33.6 |
| 8 | 35.3 | 38.7 | 38.6 | 22.3 | 32.1 | 27.3 | 27.3 |
| 9 | 66.3 | 177.5 | 176.3 | 22.5 | 68.5 | 22.4 | 22.2 |
| 10 | 16.8 | 17.0 | 16.9 | 16.5 | 22.4 | 22.4 | |
| 1′ | 129.7 | 130.5 | 130.5 | 130.3 | 130.5 | 130.3 | 130.4 |
| 2′ | 102.7 | 111.6 | 111.6 | 111.7 | 111.6 | 111.7 | 111.7 |
| 3′ | 148.2 | 147.4 | 147.4 | 147.4 | 147.4 | 147.4 | 147.4 |
| 4′ | 132.8 | 145.3 | 145.3 | 145.4 | 145.4 | 145.4 | 145.4 |
| 5′ | 145.6 | 115.2 | 115.1 | 115.2 | 115.2 | 115.2 | 115.1 |
| 6′ | 108.1 | 119.6 | 119.6 | 119.7 | 119.7 | 119.7 | 119.7 |
| 7′ | 42.0 | 41.8 | 41.8 | 41.9 | 41.8 | 41.9 | 41.8 |
| 1″ | 174.4 | 174.6 | 174.4 | 170.1 | |||
| 2 ″ | 66.0 | 65.9 | 66.0 | 68.5 | |||
| 3″ | 20.5 | 20.5 | 20.5 | 16.8 | |||
| 1‴ | 174.1 | ||||||
| 2‴ | 65.5 | ||||||
| 3‴ | 20.3 | ||||||
| OCH3-9 | 51.3 | ||||||
| OCH3-3′ | 55.7 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 |