Table 2.

Steady-state OECT performance of polymers

Polymer		Conc. of Pd [ppm]a	µOECT [cm2 V−1 s−1]b	C* [F cm−3]c	[μC*] [F V−1 cm−1 s−1]d	gm’ [S cm−1]e
p(g4T2-TT)	Unpurified	1769	3.13 ± 0.52	120 ± 9	374 ± 67	295 ± 57
	F2	370	5.31 ± 2.65	246 ± 21	1308 ± 662	838 ± 438
	F1	323	5.65 ± 0.19	123 ± 15	694 ± 87	494 ± 17
	F3	157	6.53 ± 0.065	308 ± 20	2008 ± 130	1457 ± 6
	F4	73	8.53 ± 0.40	114 ± 14	972 ± 127	626 ± 38
	F3 + Pd2(dba)3	2157	3.02 ± 0.26	287 ± 18	860 ± 56	602 ± 21
	Recombinedf	236	4.75 ± 1.12	123 ± 17	451 ± 124	231 ± 56
p(C6g3NDI-T)	Unpurified	1176	1.02 × 10−3 ± 3.79 × 10−4	222 ± 79	0.227 ± 0.117	0.055 ± 0.021
	F4	540	2.26 × 10−3 ± 2.53 × 10−4	250 ± 78	0.563 ± 0.188	0.164 ± 0.018
	F1	197	3.57 × 10−3 ± 2.94 × 10−4	129 ± 55	0.461 ± 0.202	0.127 ± 0.017
	F3	112	6.06 × 10−4 ± 1.58 × 10−4	521 ± 160	0.316 ± 0.127	0.095 ± 0.024
	F2	39	5.34 × 10−3 ± 3.40 × 10−4	306 ± 127	1.632 ± 0.688	0.155 ± 0.020
	F2 + Pd2(dba)3	2039	1.10 × 10−3 ± 1.52 × 10−4	124 ± 26	0.136 ± 0.0341	0.029 ± 0.003
	Recombinedf	198	1.96 × 10−3 ± 2.25 × 10−4	257 ± 101	0.503 ± 0.205	0.110 ± 0.012

^aCalculated from inductively coupled plasma mass spectrometry (ICP-MS, detailed in the SI).

^bOECT mobility calculated from the transistor saturation µC* product using the respective C* values.

^cC* values extracted from Randles circuit fits from electrochemical impedance curves of the polymers coated on Au electrodes in 0.1 M aqueous NaCl solution.

^d[μC*] calculated for the highest performing channel from the slope of g_m with known channel dimensions and applied bias.

^ePeak OECT transconductance normalized by thickness.

^fFormed by combining a mass ratio of 1:1.32:0.16:1 of F1:F2:F3:F4 for p(g₄T2-TT), which resulted in M_n = 90.6 kDa and a mass ratio of 1:1.4:1.4:1 of F1:F2:F3:F4 for p(C₆g₃NDI-T), which resulted in M_n = 61.2 kDa. All measurements are an average across 6 devices.