Table 6. Computed EP Times (t1 and t2) from the Nonlinear Regressions Using the eWf and the TCa.
| endpoint time / s | ||||
|---|---|---|---|---|
| experiment | empirical W-function,teWf | theoretical curve, tTC(t) | Applied Precision, AP | % difference |
| initial titration | ||||
| 1 | 179.11 | 177.71 | 178.78 | –0.78 |
| 2 | 228.47 | 226.64 | 230.1 | –0.80 |
| 3 | 167.52 | 165.93 | 166.99 | –0.95 |
| 4 | 160.42 | 158.01 | 159.91 | –1.50 |
| 5 | 218.86 | 217.57 | 218.31 | –0.59 |
| 6 | 169.82 | 166.51 | 170.04 | –1.94 |
| 7 | 252.77 | 250.09 | 252.35 | –1.06 |
| 8 | 231.09 | 229.44 | 230.46 | –0.71 |
| 9 | 79.87 | 77.71 | 79.24 | –2.70 |
| 10 | 101.54 | 100.14 | 101.32 | –1.37 |
| final titration | ||||
| 1 | 62.17 | 61.64 | 61.89 | –0.88 |
| 2 | 62.44 | 61.28 | 62.31 | –1.86 |
| 3 | 58.51 | 58.38 | 58.43 | –1.92 |
| 4 | 59.21 | 58.02 | 59.18 | –2.02 |
| 5 | 59.41 | 58.43 | 59.35 | –1.65 |
| 6 | 62.74 | 61.58 | 62.68 | –1.85 |
| 7 | 62.33 | 61.10 | 62.26 | –1.98 |
| 8 | 61.59 | 60.57 | 61.50 | –1.66 |
| 9 | 59.83 | 58.71 | 59.72 | –1.88 |
| 10 | 59.56 | 58.51 | 59.44 | –1.77 |
The EP times given by the software of the Applied Precision instrument (AP) are also given as a reference value. The percentage of difference (% difference) is calculated with respect to the value obtained with the eWf as 100*(tTC(t) – teWf)/teWf.