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. 2022 Oct 19;122(24):17647–17695. doi: 10.1021/acs.chemrev.2c00140

Figure 8.

Figure 8

Possible trends of isosteric heat of adsorption. Trend a is typical of a solid with a finite number of strong adsorption sites and otherwise weak adsorption sites. Trend b belongs to a solid with an energetically heterogeneous surface. Trend c is typical of systems with weak adsorbent–adsorbate interactions.