Skip to main content
. 2022 Oct 19;122(24):17647–17695. doi: 10.1021/acs.chemrev.2c00140

Table 2. Relevant Properties of Adsorbates Mentioned in This Work14,54,355364.

  Tm Tb dkin Polarizability Dipole moment Quadrupole moment
Molecule (K) (K) (Å) (10–25 cm3) (10–18 esu cm) (10–26 esu cm2)
H2 18.6 20.3 2.83–2.89 8.042 0 0.662
D2 13.8 23.6 2.83–2.89 7.954 0
H2O 273.1 373.2 2.64 14.5 1.8546
N2 63.1 77.4 3.64–3.80 17.403 0 1.52
O2 54.4 90.2 3.47 15.812 0 0.39
CO 68.1 81.7 3.69 19.5 0.1098 2.50
CO2 216.6 216.6 3.30 29.11 0 4.3
CH4 90.7 111.2 3.76 25.93 0 0
C2H4 104.0 169.4 4.16 42.52 0 1.50
C2H6 90.35 184.6 4.44 44.3–44.7 0 0.65
Ethanol 159.1 351.8 4.53 51.1–54.1 1.69
C3H6 87.9 225.5 4.67 62.6 0.366
C3H8 91.45 231.0 4.30–5.12 62.9–63.7 0.084
Acetone 178.5 329.2 4.60–4.79a 63.3–64.0 2.88
n-Butane 134.8 272.7 4.69 82 0.05
Isobutane 113.5 261.3 5.28 81.4–82.9 0.132
1-Butene 88.8 266.9 4.46 81 0.36–0.44
cis-2-Butene 133.9 276.9 4.2–4.94 82 0.3
trans-2-Butene 167.3 274.0 4.3–4.6 81.82 0
1,3-Butadiene 164.3 268.6 4.31–5.2 86.4 0
Isobutene 132.5 266.3 4.84 80 0.5
1-Butanol 183.3 390.6 4.63a 1.65
n-Pentane 143.3 309.2 4.50 99.9 0
Isopentane 113.3 301.0 5.0 0.13
Neopentane 256.6 282.7 6.2–6.46 102.0 0
n-Hexane 177.8 341.9 4.3 119 0
2-Methylpentane 119.5 334.0 5.5 0.1
2,3-Dimethylbutane 173.3 331.2 6.2b
2,2-Dimethylbutane 144.3 322.9 6.3
n-Heptane 182.6 371.6 4.3 136.1 0
3-Methylhexane 154.9 365.0 5.9b
2,3-Dimethylpentane 82.6 362.9 6.2b
2,4-Dimethylpentane 153.9 353.7 5.8b
m-Xylene 225.3 412.3 6.8c, 7.1d 142 0.37
o-Xylene 248.0 417.6 6.8c, 7.4d 145 0.64
p-Xylene 286.4 411.5 5.8c, 6.7d 143 0.1
Ethylbenzene 178.18 409.4 5.8c, 6.7d 142 0.59
a

Critical diameter from ref (359).

b

Critical molecular w-h parameter from ref (361).

c

Taken from ref (355).

d

Taken from ref (14).