Skip to main content
. 2022 Dec 14;70(51):16241–16252. doi: 10.1021/acs.jafc.2c07457

Table 3. Relative Amounts of the Different Linkage Types Formed per HCAgm after 120 min of Incubation with HRP on a Small Scalea.

  relative amounts (± st. dev.)
  CouAgm FerAgm SinAgm
4-O-7′/3-8′-linkage 62.4 (± 1.7) 57.9 (± 4.1) 0.0 (± 0.0)
2-7′/8-8′-linkage 0.0 (± 0.0) 18.3 (± 0.7) 60.6 (± 0.7)
8-8′/9-N-7′-linkage 7.3 (± 0.6) 2.0 (± 0.3) 25.4 (± 1.5)
4-O-8′-linkage 4.9 (± 0.0) 14.4 (± 0.4) 0.0 (± 0.0)
8-8′-linkage 14.0 (± 0.3) 4.8 (± 0.4) 14.0 (± 0.2)
unidentified 11.3 (± 0.6) 2.6 (± 0.5) 0.0 (± 0.0)
a

Percentages are determined based on the relative UV320 peak area for all dimers. Standard deviations (st. dev.) are based on triplicates.