Figure 2.

Photoelectron spectra of the ${}^{81}{\mathrm{B}\mathrm{r}}^{-}+{\mathrm{C}\mathrm{H}}_3\mathrm{I}$ ${\mathrm{S}}_{\mathrm{N}}2$ reaction intermediates, resulting from 4.661 eV laser radiation. The inset plots are a close‐up view of spectral feature 3, as annotated in the spectra.