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. 2020 Jan 3;3:1. doi: 10.1038/s42004-019-0249-6

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© The Author(s) 2020

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 1 — a Transformation of Ph₃P(O) to a variety of organic phosphorus compounds by SD. b A vast amount of Ph₃P(O) is produced and discarded as a useless chemical waste. c Costly and dangerous methods for the preparation of organophosphorus compounds. d Selective C-P, C-H and O-P bond cleavage of triphenylphosphine oxide by SD under mild conditions. Condition a: 1 and SD in THF at 25 °C; Condition b: SD/PhCl then 1 at 25 °C, THF; Condition c: SD/PhCl, 1, then SD at 25 °C, THF.