| Crystal data |
| Chemical formula |
[Eu(C7H5O2S)3(H2O)3]·3C7H6O2S |
|
M
r
|
1128.05 |
| Crystal system, space group |
Trigonal, R3 |
| Temperature (K) |
296 |
|
a, c (Å) |
26.5369 (6), 5.9386 (1) |
|
V (Å3) |
3621.72 (17) |
|
Z
|
3 |
| Radiation type |
Mo Kα |
| μ (mm−1) |
1.62 |
| Crystal size (mm) |
0.28 × 0.22 × 0.12 |
| |
| Data collection |
| Diffractometer |
Bruker D8 QUEST CMOS |
| Absorption correction |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
|
T
min, T
max
|
0.690, 0.746 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
54319, 4921, 4921 |
|
R
int
|
0.036 |
| (sin θ/λ)max (Å−1) |
0.715 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.015, 0.032, 1.07 |
| No. of reflections |
4921 |
| No. of parameters |
252 |
| No. of restraints |
88 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
0.21, −0.25 |
| Absolute structure |
Flack x determined using 2459 quotients [(I
+)−(I
−)]/[(I
+)+(I
−)] (Parsons et al., 2013 ▸) |
| Absolute structure parameter |
−0.024 (2) |
