Table 1.

Crystal data and structure refinement details of 2·2MeOH.

Empirical formula	C32H46Cl3F6N2O2PRu
Formula weight [g mol−1]	944.17
Temperature [K]	100
Crystal System	monoclinic
Space group	I2/a
Radiation/Wavelength [Å]	Mo Ka/0.71073
Unit cell dimension [Å, deg]	a = 21.3209(5), α = 90° b = 10.5848(2), β = 99.702(2)° c = 33.3109(8), γ = 90
Volume	7410.0(3) Å3
Calculated density	1.691 Mg m−3
Z	8
Θ range [deg]	3.116–29.015
Reflections
Measured:	41,874
Independent:	8907
Observed [I > 2s(I)]:	7696
Rint	0.0411
R1 [I > 2s(I)], R1 (all)	0.0354, 0.0442
wR2 [I > 2s(I)], wR2 (all)	0.0827, 0.0883
Goodness-of-fit on F2	1.037
Largest diff. peak/hole (e Å−3)	1.032/−0.720
CCDC no.	2217194