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. 2022 Sep 21;61(43):e202210855. doi: 10.1002/anie.202210855

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© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH

This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

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Heterocyclic HTI photoswitches undergo visible light responsive double bond isomerization. Depiction of Het‐HTIs 1–16 investigated in this study and the corresponding structures in the crystalline state of Het‐HTIs Z‐1, Z‐4, E‐8, and Z‐10.