Primary crops (available studies)	Crop groups	Crops	Applications	Sampling (DAT)	Comment/Source
	Root crops	Sugar beet	Foliar: 4 × 0.29 kg/ha; interval 14 days	7 DALA: roots, tops, leaves	[U‐14C‐phenyl] prothioconazole (EFSA, 2014)
			Foliar: 4 × 0.29 kg/ha; interval 14 days	7 DALA: roots, tops, leaves	[3,5‐14C‐triazole] prothioconazole (EFSA, 2014)
	Cereals/grass	Wheat	Foliar (spring wheat): 2 × 0.22 kg/ha; BBCH 32–65	6 DALA: forage	[U‐14C‐phenyl] prothioconazole (EFSA, 2007b)
				26 DALA: hay
				48 DALA: grain and straw
			Foliar (summer wheat): 2 × 0.25 kg/ha; interval 27 days (BBCH 31–59)	0, 14 DALA: forage	[3,5‐14C‐triazole] prothioconazole‐desthio (EFSA, 2007b)
				48 DALA: grain and straw
			Foliar (spring wheat): 2 × 0.18/0.29 kg/ha; BBCH 32–65	Forage, hay, grain, straw	[3,5‐14C‐triazole] prothioconazole (EFSA, 2014)
			Seed (spring wheat): 1 × 0.02 or 0.10 kg/100 kg seeds (ca. 220 kg seeds/ha)	57 DAT: forage	[U‐14C‐phenyl] prothioconazole (EFSA, 2007b)
				110 DAT: hay
				153 DAT: grain and straw
	Pulses/oilseeds	Peanuts	Foliar: 3 × 0.3 kg/ha; interval 21 days (BBCH 66–75)	14 DALA: hays and nuts without shells	[U‐14C‐phenyl] prothioconazole (EFSA, 2007b)
			Foliar: 3 × 0.3 kg/ha; interval 21 days (BBCH 66–75)	14 DALA: hays and nuts without shells	[3,5‐14C‐triazole] prothioconazole (EFSA, 2014)
Rotational crops (available studies)	Crop groups	Crops(s)	Applications	PBI (DAT)	Comment/Source
	Root/tuber crops	Turnips	Soil, 1 × 580 g/ha	28, 146, 269	[U‐14C‐phenyl] prothioconazole (EFSA, 2007b; FAO, 2008a, 2008b); 2.9 N onion/ shallot/ garlic GAP; Crops of the 1st, 2nd and 3rd rotation were sown at day 28, 149 and 269, respectively. Sampling was done: Turnip roots and tops: 94, 201, 349 DAT; Swiss chard leaves: 80, 188, 348 DAT; Grain and straw: 145, 269, 412 DAT; Wheat green material: 73, 178, 327 DAT; Wheat hay: 111, 231, 377 DAT.
	Leafy crops	Swiss chards
	Cereal (small grain)	Spring wheat
	Root crops Leafy vegetables Cereal (small grain)	Turnips Swiss chards (leaves) Wheat	Soil, 4 × 204 g/ha	30, 125, 366	[triazole‐3,5‐14C] prothioconazole (FAO, 2008a, 2008b; EFSA, 2014;Netherlands, 2021) 4.1 N onion/ shallot/ garlic GAP; Crops of the 1st, 2nd and 3rd rotation were sown at day 30, 125 and 366, respectively. Sampling was done: Turnip roots and tops: 113, 195, 420 DAT; Swiss chard leaves: 77, 169, 406 DAT;Swiss chard leaves: 77, 169, 406 DAT; Grain and straw: 121, 209, 450 DAT; Wheat green material: 62, 154, 388 DAT; Wheat hay: 80, 171, 420 DAT.
Processed commodities (hydrolysis study)	Conditions		Stable?		Comment/Source
	Pasteurisation (20 min, 90°C, pH 4)		yes		Prothioconazole degrades to prothioconazole‐desthio under sterilisation process (≤ 11% AR). Prothioconazole‐desthio remains stable (99.4–99.9% of AR) (United Kingdom, 2018a)
	Baking, brewing and boiling (60 min, 100°C, pH 5)		yes
	Sterilisation (20 min, 120°C, pH 6)		yes
	Pasteurisation (20 min, 90°C, pH 4)		Yes		Triazole‐UL‐14C labelled triazole alanine, triazole acetic acid, triazole lactic acid and 1,2,4‐Triazole; remain stable under sterilisation processes (96.4–100.5% of AR) (United Kingdom, 2018b).
	Baking, brewing and boiling (60 min, 100°C, pH 5)		Yes
	Sterilisation (20 min, 120°C, pH 6)		Yes