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. 2022 Oct 18;61(47):e202211732. doi: 10.1002/anie.202211732

Scheme 2.

Scheme 2

Proposed mechanistic paths for: cross‐electrophile coupling (right) and 1,2‐HAT process to deliver the postulated C‐centered radical VIII (NPhth: phthalimide, left). Computations have been performed at the PCM(N,N‐dimethylacetamide) [19] ‐M06/def2svpp [20] computational level. Counterions have been disregarded in this scheme for the sake of clarity but considered in the simulations (see Supporting Information for further details).