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. 2022 Dec 23;8(1):1476–1485. doi: 10.1021/acsomega.2c06910

Table 7. Virtual Frequency Energy and Bond Length Data of Each Reaction Stagnation Point in the Oxidation Process of the −O–CH2–CH3 Structure.

structure name virtual frequency (cm–1) energy (Hartree) atomic relationship bond length (Å)
R none –536.2723 R(3,12) 1.357
R(12,13) 1.426
R(13,16) 1.512
TS1 –54.31 –536.2649 R(3,12) 1.359
R(12,13) 1.422
R(13,16) 1.514
IM1 none –536.2573 R(3,12) 1.364
R(12,13) 1.412
R(13,16) 1.519
IM2 none –536.2811 R(3,12) 1.371
R(12,13) 1.406
R(13,16) 1.527
TS2 –246.04 –536.2320 R(3,12) 1.369
R(12,13) 1.406
R(13,16) 1.522
IM3 none –536.3617 R(3,12) 1.362
R(12,13) 1.391
R(13,16) 1.497